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Selective Electrocatalytic Oxidation of Ammonia by Ru-dpp Complexes Containing Aromatic Nitrogen Donor as Axial

Shan Zhao1, Xi Zhang1, Guo Chen1

  • 1College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, P. R. China.

Inorganic Chemistry
|November 25, 2024
PubMed

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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