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Micelles

Micelles

Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...

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Related Experiment Video

Updated: Jun 11, 2026

Preparation of Thermoresponsive Nanostructured Surfaces for Tissue Engineering

Preparation of Thermoresponsive Nanostructured Surfaces for Tissue Engineering

Published on: March 1, 2016

Mimicking on-water surface synthesis through micellar interfaces.

Anupam Prasoon^1,2, Shaik Ghouse¹, Nguyen Ngan Nguyen^1,2

¹Center for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062, Dresden, Germany.

Nature Communications

|December 3, 2024

Summary

Researchers mimicked on-water surface chemistry using micelles, enabling enhanced reactivity and selectivity for fourteen chemical reactions. This micellar approach facilitates two-dimensional polymerization, broadening synthetic applications.

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Fabrication of Spherical and Worm-shaped Micellar Nanocrystals by Combining Electrospray, Self-assembly, and Solvent-based Structure Control

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Last Updated: Jun 11, 2026

Preparation of Thermoresponsive Nanostructured Surfaces for Tissue Engineering

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Fabrication of Spherical and Worm-shaped Micellar Nanocrystals by Combining Electrospray, Self-assembly, and Solvent-based Structure Control

Published on: February 11, 2018

Area of Science:

Materials Science
Organic Chemistry
Supramolecular Chemistry

Background:

The on-water surface offers unique chemical properties like enhanced reactivity and selectivity, ideal for synthesis.
Current on-water surface synthesis is limited by the need for a stable air-water interface, restricting its applications.

Purpose of the Study:

To develop a method mimicking on-water surface chemistry using micelles.
To demonstrate the utility of this micellar approach for diverse chemical reactions and 2D polymerization.

Main Methods:

Utilized self-assembled charged surfactant molecules above their critical micelle concentration (CMC) to form micellar structures.
These micelles create a confined hydrophobic core and aqueous shell environment, simulating the air-water interface.
Employed porphyrin-based monomers within these micelles to achieve controlled reactivity and selectivity.

Main Results:

Achieved high reactivity and selectivity (≥99%) in fourteen distinct reversible and irreversible chemical reactions.
Successfully synthesized crystalline two-dimensional (2D) polymer thin layers via polymerization on micellar interfaces.
Demonstrated the broad applicability of the micellar approach for various synthetic challenges.

Conclusions:

Micellar systems effectively mimic on-water surface chemistry, overcoming limitations of traditional methods.
This strategy significantly expands the accessibility of advanced surface chemistry for materials synthesis.
The approach enables efficient aqueous synthesis of complex structures like 2D polymers.