Built-in electric field guides oxygen evolution electrocatalyst reconstruction

Creating a built-in electric field (BIEF) in catalysts represents an effective strategy to promote electron transfer and induce asymmetric charge distribution, thereby facilitating surface dynamic reconstruction under oxygen evolution reaction (OER) conditions. This review summarizes recent advancements in the field of OER electrocatalysts, with a focus on regulating the work function of components to tailor the BIEFs to guide surface reconstruction processes. It also discusses the importance of surface reconstruction in improving electrocatalytic performance and the influence of BIEFs on the reconstruction of catalysts. By analyzing various strategies for manipulating electric fields for guiding surface reconstruction of OER electrocatalysts, along with numerous representative examples, this review highlights how these techniques can enhance catalytic activity and stability. The findings underscore the potential of engineered BIEFs as a powerful tool in the design of next-generation electrocatalysts, paving the way for more efficient energy conversion technologies.