Exploring, sampling, and interpreting lunar volatiles in polar cold traps

Numerous missions to the Moon have identified and documented volatile deposits associated with permanently shadowed regions. A series of science goals for the Artemis Program is to explore these volatile deposits and return samples to Earth. Volatiles in these reservoirs may consist of a variety of species whose stable isotope characteristics could elucidate both their sources and the processes instrumental in their formation. For example, the δD of potential contributors to the deposits can be used to identify a uniquely light solar wind component. Because of the exceptionally low temperatures of these volatile deposits, examining and interpreting their stable isotope systems to fulfill Artemis science goals through sampling, preserving, curating, and analyzing these samples are far more difficult than for other sample return missions. Collecting and preserving the samples at cryogenic temperatures dramatically increases science yield but is technologically demanding and poses increased risk during transport.