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Detecting Honey Adulteration: Advanced Approach Using UF-GC Coupled with Machine Learning
Irene Punta-Sánchez1, Tomasz Dymerski2, José Luis P Calle1
1Department of Analytical Chemistry, Faculty of Sciences, University of Cadiz, Agrifood Campus of International Excellence (ceiA3), IVAGRO, 11510 Puerto Real, Spain.
Detecting honey adulteration is now more reliable using ultra-fast gas chromatography (UF-GC) combined with machine learning (ML). This novel approach accurately identifies adulterants in honey, ensuring food authenticity.
Area of Science:
- Food Chemistry
- Analytical Chemistry
- Data Science
Background:
- Honey adulteration poses a significant threat to consumer trust and market integrity.
- Existing detection methods can be time-consuming, costly, or lack comprehensive accuracy.
- The need for rapid, reliable, and cost-effective analytical techniques for food authenticity is paramount.
Purpose of the Study:
- To develop and validate a novel method for detecting honey adulteration.
- To integrate ultra-fast gas chromatography (UF-GC) with machine learning (ML) for enhanced analytical performance.
- To assess the efficacy of Support Vector Regression (SVR) and Least Absolute Shrinkage and Selection Operator (LASSO) models in predicting honey adulteration.
Main Methods:
- Ultra-fast gas chromatography (UF-GC) was employed for rapid sample analysis.
- Machine learning models, specifically SVR and LASSO, were trained and applied to GC data.
- Models were evaluated for their predictive accuracy in detecting adulteration in orange blossom (OB) and sunflower (SF) honeys.
Main Results:
- The SVR model demonstrated high predictive power (R² > 0.90) for combined honey types.
- Treating OB and SF honeys individually significantly improved accuracy, with R² values exceeding 0.99.
- The LASSO model showed particular effectiveness when applied to individual honey types.
Conclusions:
- The integration of UF-GC and ML provides a robust and reliable method for honey adulteration detection.
- This approach offers a significant advancement over traditional methods, ensuring honey authenticity.
- The methodology holds potential for application in authenticating other food products, advancing food safety standards.
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