Effect of smectic polymers on cholesteric liquid crystals

Composite materials made of polymers and liquid crystals have been widely employed in smart windows, optical filters, and bistable displays. However, it is often difficult to decipher the role of the polymer network architecture on the alignment and the texture of liquid crystals. In this study, we use a simple model system where a small amount of polymerizable liquid crystalline monomer is mixed in a liquid crystal that exhibits both a smectic phase and a cholesteric phase with a large helical pitch. By cross-linking the monomer in the smectic phase, the liquid crystal textures become significantly altered. The existence of a polymer network not only creates resistance to form a helix and therefore hinders the formation of cholesteric fingerprints but also modifies the structure of the cholesteric texture. We investigate the effects of changing the concentration of chiral dopant and monomer on the formation and growth of the cholesteric fingerprint texture during the phase transition and on the width of the fingerprints. We find that, within a certain parameter range, the cholesteric fingerprints do not depend on the concentration of the chiral dopant. We explain this phenomenon by hypothesizing that the polymer network acts as a bulk alignment field.