N skeleton-regulated cobalt phthalocyanine promotes polysulfide adsorption and redox kinetics
Jiaqi Zhao1, Zhanwei Xu1, Yujiao Zhang2
1Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, P. R. China. xuzhanwei@sust.edu.cn.
Abstract:
An N skeleton substituent on cobalt phthalocyanine (CoPc) was meticulously studied to redistribute the charge in phthalocyanine, improve the mass diffusion, and promote the redox kinetics of polysulfides (LiPS), resulting in a significant ultra-low capacity decay of 0.11% at 5C over 500 cycles.


