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Two novel lanthanide metal-organic frameworks based on tetraphenylethylene for ultra-high proton conduction

Qi Wu1, Qianxi Li1, Wenkang Zou1

  • 1School of Chemical Science and Technology, Yunnan University, Kunming 650500, P. R. China. yanzhou@ynu.edu.cn.

Chemical Communications (Cambridge, England)
|January 6, 2025
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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...