Te₂-Regulated Black Arsenic Phosphorus Monocrystalline Film with Excellent Uniformity for High Performance...

Two-dimensional (2D) black arsenic phosphorus (b-AsP) material has been attracting considerable attention for its extraordinary properties. However, its application in large-scale device fabrication remains challenging due to the limited scale and irregular shape. Here, we found the special effect of Te₂ upon growth of b-AsP and developed a novel Te₂-regulated steady growth (Te-SG) strategy to obtain high-quality b-AsP single crystal. The large-scale b-AsP single crystal sheet with its full width at half-maximum (FWHM) being ≤0.05° was achieved for the first time. The b-AsP monocrystalline film with atomic-level flat surface was further fabricated by laser, which exhibits outstanding self-powered characteristics under various light illumination, including low dark current and peak room-temperature detectivity of 8.5 × 10¹⁰ cm Hz^1/2 W^-1. The excellent uniformity was also revealed through a large-plane b-AsP photodetector. This work paves a new way for the application of high-performance electronics and optoelectronics based on b-AsP.