Stiffer Is Stickier: Adhesion in Elastic Nanofilms

When two objects are brought into contact, separating them typically requires overcoming a detachment force. While this adhesion-induced force is vital for thin film materials in a range of nature and engineering systems, its quantitative understanding remains elusive due to the complex interplay between nonlinear deformation and adhesion. Here we perform controlled experiments and develop formal theories for the detachment force in a canonical configuration: separation of a sphere from an elastic graphene film. We observe that applying tension to the film can increase both its apparent out-of-plane stiffness and its detachment force, a behavior that cannot be explained by macroscopic adhesion theories. We attribute this unusual "stiffer-stickier" behavior to long-range intermolecular forces and demonstrate that it is a general phenomenon for elastic nanofilms, explainable through a multiscale theory that we develop. The ideas introduced here offer a generic strategy to understand the adhesion of slender structures across various length scales.