The need for robust model systems in the study of hybrid interfaces for photocatalysis and photoelectrocatalysis

Small molecule conversion to value-added products using renewable energy sources has emerged as a promising strategy to mitigate our reliance on fossil fuels. Hybrid materials that integrate the strengths of photoabsorbers and co-catalysts (electrocatalysts) are essential for maximizing the efficiency of photochemical (PC) and photoelectrochemical (PEC) systems. In this perspective, we will focus on the need for fundamental studies with a strong emphasis on the importance of beginning with well-defined hybrid interfaces. A particular focus is given to small molecule adsorption studies that correlate surface structure and chemistry to reactivity, highlighting its potential in characterizing complex interfaces. We also make the case for understanding how light and electrochemical environments influence surface structure, adsorption, and reactivity and should be considered in model hybrid system design. Finally, we provide a framework to connect the theory and experiment of model hybrid surfaces to provide a molecular understanding of PC and PEC at these interfaces and accelerate our integration of these materials into real systems capable of meeting our renewable energy needs.