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Published on: December 6, 2021
Oxygen-Doped γ-Mo2N as High-Performance Catalyst for Ammonia Decomposition
Yi Shi1,2,3, Xiao Wang1,2,3, Lingling Zhang1,3
1State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
Abstract:
γ-Mo2N catalysts exhibit excellent activity and stability in ammonia decomposition reactions. However, the influence of oxygen on its activity is still unknown. In this work, two γ-Mo2N catalysts with different oxygen content are synthesized using temperature-programmed nitridation of α-MoO3. The γ-Mo2N catalysts are highly oxidized and their ammonia decomposition performance is closely related to their oxygen content. The activity of γ-Mo2N with high oxygen content (HO-γ-Mo2N) is much higher, whose H2 formation rate at 550 °C is 3.3 times higher than the γ-Mo2N with low oxygen content (LO-γ-Mo2N). This is mainly attributed to two aspects: on the one hand, the higher valence state of Mo in the HO-γ-Mo2N leads to stronger Mo─NH3 bonds, which promotes the adsorption and activation of NH3. On the other hand, the H generated by N─H bond breaking is more easily migrated to O, which avoids excessive H occupying the γ-Mo2N active sites and alleviates the negative effect of hydrogen poisoning.
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