Metal Doped Multicomponent Copper-Based Arrays for Formaldehyde Oxidation Assisted Dual Hydrogen Production System

Green hydrogen production technology is an effective strategy for solving energy problems and environmental issues. In this paper, we report a bipolar hydrogen production system: Au-CuO/CF∥Ru-CuO/CF, in which the cathode produces hydrogen through the hydrogen evolution reaction (HER) process and the anode produces hydrogen through a formaldehyde oxidation reaction (FOR). It is found that when Au-CuO/CF is used in FOR, the C-H bond of formaldehyde will be broken at low potential to produce reactive hydrogen H*. H* is recombined through the Tafel step (H* + H* ⇌ H₂) to produce H₂. At the same time, the formaldehyde is oxidized to a high-value-added product HCOOH. We found that the formation of grain boundary-rich structures on the Au-CuO surface jointly promotes the oxidation of formaldehyde at low potentials. In addition, we introduced Ru elements into CuO to enhance the cathodic HER. The FOR-HER system of Au-CuO/CF∥Ru-CuO/CF was tested in a flow cell. It produced a current density of 500 mA cm^-2 at a potential of only 0.38 V. This work provides system construction and catalyst design ideas for bipolar hydrogen production at low voltages.