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Updated: May 24, 2025
Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
Published on: February 10, 2023
Solvent-mediated subcomponent self-assembly of covalent metallacycles for hierarchical porous materials synthesis
Zhi-Wei Li1,2, Anlian Huang2, Zhenguo Wang1,2
1Northeast Guangdong Key Laboratory of New Functional Materials, School of Chemistry and Environment, Jiaying University, Meizhou, 514015, China. lizhw69@mail.sysu.edu.cn.
Abstract:
We report a solvent-mediated subcomponent self-assembly strategy for synthesizing tetranuclear and triangular covalent metallacycles. The results demonstrate that the polarity of solvent significantly influences the structural outcome of metallacycles, and the square-shaped metallacycles can serve as building blocks for the construction of hierarchical porous materials such as metallacycle-based hydrogen-bonded organic frameworks (mHOFs) and metal-organic frameworks (mMOFs).
