Related Experiment Video
Updated: May 23, 2025

06:50
Preparation and 3D Tracking of Catalytic Swimming Devices
Published on: July 1, 2016
7.5K
The motion of catalytically active colloids approaching a surface.
Julio Melio1, Solenn Riedel1, Ali Azadbakht1
1Huygens-Kamerlingh Onnes Laboratory, Leiden University, P.O. Box 9504, 2300 RA Leiden, The Netherlands. kraft@physics.leidenuniv.nl.
Soft Matter
|March 11, 2025
Summary
Researchers used acoustic tweezers to study catalytic microswimmers near walls. They found that wall proximity and salt concentration reduce microswimmer speed, impacting propulsion mechanisms and highlighting ionic effects.
Area of Science:
- Physics
- Chemistry
- Materials Science
Background:
- Catalytic microswimmers often aggregate near surfaces due to hydrodynamic and phoretic interactions.
- Wall proximity complicates the analysis of intrinsic catalytic propulsion mechanisms.
Purpose of the Study:
- To investigate the propulsion dynamics of catalytic Janus spheres away from walls using acoustic tweezers.
- To decouple wall effects from intrinsic catalytic propulsion and understand ionic influences.
Main Methods:
- Utilized acoustic tweezers to levitate Janus microswimmers at varying heights from a substrate.
- Analyzed mean-squared displacement to determine diffusion constants and mobility.
- Measured microswimmer velocity as a function of height and salt concentration.
Main Results:
- Diffusion constants align with Faxén's predictions for near-wall hydrodynamic mobility.
- Microswimmer velocity decreases with increasing salt concentration, indicating reduced propulsion.
- Velocity-height profiles follow hydrodynamic scaling, suggesting wall-swimmer coupling.
Conclusions:
- Wall proximity and ionic strength significantly influence microswimmer speed and propulsion.
- Observed speed reduction with salt addition generally matches electrokinetic theory.
- An anomaly in bulk 0.1 wt% H2O2 suggests potential alternative propulsion mechanisms.
Related Concept Videos
Colloidal precipitates
477
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
477
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Colloids and Suspensions
1.6K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.6K
Coagulation
256
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
256
Surface Tension, Capillary Action, and Viscosity
27.4K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.4K
Contact Angle
11.6K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
11.6K

