Morphological advances and innovations in conjugated polymer films for high-performance gas sensors

Conjugated polymers (CPs) are considered one of the most important gas-sensing materials due to their unique features, combining the benefits of both metals and semiconductors, along with their outstanding mechanical properties and excellent processability. However, CPs with conventional morphological structures, such as largely amorphous and bulky matrices, face limitations in practical applications because of their inferior charge transport characteristics, low surface area, and insufficient sensitivity. Therefore, the design and development of novel morphological nanostructures in CPs have attracted significant attention as a promising strategy for improving morphological and electrical characteristics, thereby enabling a considerable increase in the sensing performance of corresponding gas sensors. Numerous CP nanostructures have been developed and implemented for high-performance gas sensors. Highlighting the morphological advances and bottlenecks of these nanostructures is crucial for providing an overview of developing trends, potential strategies, and emerging areas for the future development of CP nanostructures in the field. In this regard, this study describes state-of-the-art CP nanostructures, emphasizing their attractive morphological and electrical characteristics to help readers and researchers better understand emerging trends, promising future directions, and key obstacles for the application of CP nanostructure-based gas sensors. The most crucial aspects of CP nanostructures, including advanced preparation techniques, morphological properties, and sensing characteristics, are discussed and assessed in detail. Moreover, development strategies and perspectives for achieving high sensing efficiency in CP nanostructure-based flexible and wearable sensors are summarized and emphasized.