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Synthesis of the aggregation pheromone of Tribolium castaneum
Biyu An1, Xueyang Wang1, Ao Jiao2
1Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, China.
Beilstein Journal of Organic Chemistry
|March 13, 2025
Abstract:
Tribolium castaneum Herbst is a destructive stored product pest. The aggregation pheromone of this pest was prepared via a new and effective strategy. The key steps include the ring-opening reaction of chiral 2-methyloxirane, the stereospecific inversion of chiral secondary tosylate, Li2CuCl4-catalyzed coupling of tosylate with Grignard reagent, and oxidation with RuCl3/NaIO4.
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