Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Formation of Complex Ions03:45

Formation of Complex Ions

23.1K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.1K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Enhanced Kinetics of Lithium-Ion Charge Storage on Si Anode through Ultrasmall Magnesium Nitride Nanoparticles toward Fast and Durable All-Solid-State Lithium-Ion Batteries.

ACS applied materials & interfaces·2026
Same author

Boosting electronic and Li<sup>+</sup> transport in silicon <i>via</i> titanium nitride incorporation for high-performance all-solid-state lithium-ion batteries.

Chemical communications (Cambridge, England)·2026
Same author

Chemically coupled dual-interface self-regulation for perovskite solar cells.

Nature communications·2026
Same author

Spherulite-packed polymer electrolytes with high ion selectivity for stable lithium-sulfur battery performance.

Chemical communications (Cambridge, England)·2026
Same author

Lithium-rich disordered rock salt Li<sub>1.25</sub>V<sub>0.5</sub>Nb<sub>0.25</sub>O<sub>2</sub> as the anode material for lithium-ion capacitors.

Chemical communications (Cambridge, England)·2026
Same author

Modulation of Ion Distributions and Electroneutrality inside Nanopores by Ion Transport under Electric Fields.

ACS applied materials & interfaces·2026

Related Experiment Video

Updated: May 22, 2025

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
07:20

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

2.5K

Melt-Infusion-Induced Electrolyte Surface Coating Stabilized Sulfide-Based All-Solid-State Lithium Metal Batteries.

Shuxian Zhang1, Qingyu Li1, Jing Gao1

  • 1Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University, Jinan 250061, China.

ACS Nano
|March 14, 2025
PubMed
Summary

A novel artificial coating for sulfide solid-state electrolytes enhances lithium metal battery safety and performance. This coating improves ion transport and suppresses dendrite growth, enabling stable cycling and high energy density.

Keywords:
Li metalLi5.5PS4.5Cl1.5all-solid-state lithium metal batteriesartificial coatingmelt -infusion

More Related Videos

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

21.6K
Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
10:41

Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries

Published on: May 22, 2018

36.5K

Related Experiment Videos

Last Updated: May 22, 2025

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
07:20

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

2.5K
Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

21.6K
Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
10:41

Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries

Published on: May 22, 2018

36.5K

Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Sulfide-based all-solid-state lithium metal batteries (ASSLBs) offer high energy density but suffer from interfacial degradation.
  • This degradation impedes lithium-ion (Li+) transport and causes uneven lithium deposition, limiting battery performance and safety.

Purpose of the Study:

  • To develop an artificial coating for sulfide solid-state electrolytes (SSEs) to mitigate interfacial issues in ASSLBs.
  • To enhance Li+ transport, suppress lithium dendrite formation, and improve the overall stability and performance of ASSLBs.

Main Methods:

  • A melt-infusion method was employed to apply lithium trifluorosulfonylimide (LiTFSI) as an artificial coating on Li5.5PS4.5Cl1.5 (LPSCl) particles.
  • Experimental characterization and theoretical calculations were used to analyze the coating's effect on the solid electrolyte interphase (SEI) and interfacial properties.

Main Results:

  • The LiTFSI coating effectively mitigated interfacial side reactions, promoting a LiF/Li3N-rich SEI.
  • This enhanced SEI accelerated Li+ transport and suppressed lithium dendrite growth, achieving a critical current density (CCD) of 3.1 mA cm-2.
  • Li-symmetric cells demonstrated stable operation for 900 hours at 2 mA cm-2.
  • ASSLBs with coated SSEs achieved 90.2% capacity retention over 1000 cycles at 2C and stable cycling with high LiCoO2 loading (28.5 mg cm-2).

Conclusions:

  • The proposed artificial coating strategy significantly improves the interfacial stability and electrochemical performance of sulfide-based ASSLBs.
  • The LiF/Li3N-rich SEI is crucial for enabling high critical current densities and long-cycle life in these advanced battery systems.
  • This approach holds promise for the practical application of safe and high-energy all-solid-state lithium metal batteries.