Two-dimensional nanostructures of transition metal-based materials towards aqueous electrochemical energy storage

Transition metal-based materials have garnered considerable attention in the energy storage field owing to their diverse composition, abundant redox capacity and excellent thermal stability. However, the application of these materials as electrodes for aqueous electrochemical energy storage devices such as aqueous zinc-ion batteries (AZIBs) and supercapacitors (SCs) is impeded by their low conductivity and limited energy density. This challenge can be effectively addressed through structural optimizations of transition metal-based materials. In recent years, extensive research has been conducted on two-dimensional (2D) nanostructured transition metal-based electrodes in the context of AZIBs and SCs, thereby presenting promising prospects for 2D nanostructures of transition metal-based materials. This review provides a comprehensive overview of the synthesis methods for 2D nanostructured materials and presents research findings on 2D nanostructured transition metal-based electrodes in AZIBs and SCs. It analyzes the advantages of 2D nanostructures, focusing on transition metal oxides, hydroxides, and sulfides. Furthermore, it explores the correlation between their structural characteristics and electrochemical properties. Finally, we discuss the main challenges faced by 2D nanostructures of transition metal-based materials and outline future development prospects.