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Updated: May 21, 2025
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Modulating the electronic configuration of single-atom nanozymes using cobalt nanoclusters for enhanced mycotoxin
Yaqi Zhang1, Huikang Lin1, Lan Wang1
1CAS Key Laboratory of Nutrition, Metabolism and Food Safety, Shanghai Institute of Nutrition and Health, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200031, China.
Abstract:
Herein, Co- and Fe-based single-atom nanozymes (M/N-PC, M = Co or Fe) were successfully fabricated and their catalytic performances for patulin degradation were evaluated systematically. Co/N-PC, consisting of Co-N4 and nanoclusters sites, achieved a higher patulin degradation efficiency (99.4 %, within 60 min) than Fe/N-PC (only consisting of Fe-N5 sites). Synergistic interactions between Co-N4 and Co nanoclusters greatly enhanced electron density near the Fermi level in Co/N-PC, enabling its high catalytic performance. The degradation products of patulin exhibited negligible cytotoxicity. The M/N-PCs demonstrated good reusability, broad pH adaptability and high practical application potential for patulin degradation in apple juice. M/N-PC also exhibited high efficiency in degrading aflatoxin B1, deoxynivalenol and zearalenone (∼100 %, 10-40 min). This study provides in-depth insights into the relationship between metal active site structures in M/N-PCs and their catalytic properties for mycotoxin detoxification, offering guidance for the design of highly efficient single-atom nanozymes.
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