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Strategic Material Design for Highly Reliable QLC 3D V-NAND Using Bypass Resistive Random Access Memory
Geonhui Han1, Jongseon Seo1, Junghoon Park2
1Center for Single Atom-based Semiconductor Device and the Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 37673, Korea.
ACS Applied Materials & Interfaces
|March 24, 2025
Summary
Researchers developed design guidelines for electrochemical random-access memory (ECRAM) to achieve uniform quadruple-level cell (QLC) operation in V-NAND flash memory. This breakthrough enables precise control over oxygen vacancy migration for enhanced memory performance.
Area of Science:
- Materials Science
- Electrical Engineering
- Solid-State Physics
Background:
- Conventional flash memory faces limitations, prompting research into alternatives like electrochemical random-access memory (ECRAM).
- Bypass RRAM shows promise for V-NAND applications due to its ion hopping conduction, but parameters for multilevel cell (MLC) operation are not fully understood.
Purpose of the Study:
- To establish design guidelines for bypass RRAM enabling highly uniform quadruple-level cell (QLC) operation.
- To explore the impact of quantized oxygen vacancy (Vo) injections on memory characteristics.
Main Methods:
- Material engineering was employed to precisely control ion migration in bypass RRAM.
- The study utilized the unique electrical properties of the WO resistive switching (RS) layer to minimize Vo migration.
- MATLAB simulations and experimental results were used to identify key parameters like ionic barrier (Ea,ion) and ion diffusivity (Dion).
Main Results:
- Achieved low-voltage operation (<5 V) and a high on/off ratio (>106) with minimal stoichiometry change (Δx < 0.08).
- Optimized parameters resulted in superior QLC performance with highly uniform distribution (σ/μ ∼ 0.01) and sensing margin (ΔG ∼ 4 μS).
- Demonstrated the absence of read disturbance issues in the optimized bypass RRAM.
Conclusions:
- The developed design guidelines facilitate highly uniform QLC operation in bypass RRAM for V-NAND memory.
- Reduced Vo migration at the nanoscale suggests potential for extending beyond QLC levels with quantized Vo injection.
- This research provides a pathway for highly uniform switching in next-generation V-NAND memory technologies.

