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Asymmetric Co-Ru Heterostructure Catalyst for Surface-Plasmon-Enhanced Photothermocatalytic CO Hydrogenation to Fuels
Zhaoda Xie1, Xi-Yang Yu1, Zelin Zhang2
1Institute of Industrial Catalysis, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, P. R. China.
Abstract:
Photothermal Fischer-Tropsch synthesis (FTS) aims to convert carbon monoxide (CO) into value-added long-chain hydrocarbons (C5+) under milder conditions, but the efficient C-C coupling of C1 intermediates remains challenging. Herein, a carbon-supported plasmonic CoRu5@C catalyst has been successfully constructed for promoting C-C coupling. Experimental results demonstrate that under ambient pressure and photothermal conditions at 250 °C, CoRu5@C exhibits a C5+ selectivity of 98.9% and FTS activity of 321.4 mmol gcat-1 h-1. Structural characterizations and finite element method simulations indicate that Ru-induced lattice strain in the Co-Ru heterogeneous catalyst boosts energetic charge carrier migration, promoting CO adsorption and activation. A series of in situ experiments reveal that electron-rich Co sites in the Co-Ru heterogeneous catalyst diminish C1 intermediate repulsion, boosting C-C coupling efficiency in the FTS process. This research not only provides an innovative approach to overcoming the challenges in CO hydrogenation selectivity and the synthesis of high-value fuels but also offers significant contributions to the development of sustainable energy technologies.
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