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Types of Step-Growth Polymers: Polyesters01:20

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Recyclable and Biodegradable Paper Coating with Functionalized PLA and PBAT.

Syeda Shamila Hamdani1, Hazem M Elkholy1, Manal O Alghaysh1

  • 1School of Packaging, Michigan State University, 448 Wilson Road, East Lansing, Michigan 48824-1223, United States.

ACS Omega
|March 31, 2025
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Summary
This summary is machine-generated.

New functionalized polyester coatings offer recyclable and compostable paper solutions. This innovation addresses packaging waste by creating eco-friendly, PFAS-free coated paper for a circular economy.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Sustainable Packaging

Background:

  • Conventional polyester-coated paper is widely used for packaging but poses significant environmental challenges due to its non-recyclable nature.
  • The persistence of non-biodegradable materials in packaging contributes to landfill waste and microplastic pollution.

Purpose of the Study:

  • To develop novel, recyclable, and industrially compostable paper coating materials.
  • To create a sustainable alternative to conventional non-recyclable polyester coatings for packaging applications.
  • To ensure the developed coatings are free from harmful substances like PFAS and persistent microplastics.

Main Methods:

  • Synthesis of carboxylic acid-functionalized polylactic acid (CPLA) and poly(butylene adipate-co-terephthalate) (CPBAT).
  • Application of CPLA, or CPLA/CPBAT blends, as emulsified coatings onto paper.
  • Comprehensive testing of coated paper for barrier properties, repellency, sealing, mechanical strength, repulpability, recyclability, and compostability.

Main Results:

  • The functionalized polyester-coated papers demonstrated excellent water and oil repellency, gas and moisture barrier properties, and sealing capabilities.
  • Certified testing validated the repulpability and recyclability of the coated papers.
  • Industrial compostability of the coated papers was confirmed, and they were found to be free of PFAS and persistent microplastics.

Conclusions:

  • Functionalized polyester blends provide a viable and sustainable solution for paper coatings.
  • The developed coated paper meets performance requirements for packaging while aligning with circular economy principles.
  • This innovation offers an environmentally responsible alternative to conventional coated papers, reducing plastic waste and promoting biodegradability.