Next-generation stimuli-responsive smart membranes: Developments in oil/water separation

Effective treatment of oil-contaminated wastewater is essential due to its severe environmental and health impacts. The membrane-based separation is cost-effective, energy-efficient, and eco-friendly; however, fouling has remained a pressing issue. Stimuli-responsive membranes, which adjust their pore structure and surface properties in response to external triggers such as light, pH, and temperature, offer enhanced fouling resistance and improved separation performance. This review provides a comprehensive analysis of stimuli-responsive membranes for oil/water separation, emphasizing the role of smart polymeric materials engineered for controllable separation processes. We critically assess the strengths of these advanced membranes, including their tuneable wettability and energy-efficient operation, while identifying key limitations such as long-term stability, response time, scalability, and cost-effectiveness. Furthermore, the review explores various polymer types, synthesis methods, and fabrication techniques, evaluating their effectiveness in separation applications. Finally, the review concludes by outlining the challenges and proposing future directions to enhance the performance of stimuli-responsive membranes. By offering valuable insights into the dynamic control of membrane structures and properties, this study aims to inspire the development of next-generation stimuli-responsive membranes, drive their commercialization, and promote sustainable water treatment solutions.