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Updated: May 16, 2025

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
Published on: April 27, 2018
Hollow CoNiFe ternary metal selenide electrocatalysts derived from Prussian blue analogues for boosting the oxygen
Mingyang Cai1, Weishun Song1, Ziling Huang1
1Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, P. R. China. xqcao2022@sina.com.
Abstract:
The development of effective electrocatalysts is a top priority for the oxygen evolution reaction (OER), which is the crucial half-reaction of water electrolysis, since electrocatalytic water splitting for hydrogen production offers a practical solution to the upcoming energy crisis. Herein, we report a strategy to fabricate hollow ternary metal selenide (CoNiFe-Se) nanocubes derived from Prussian blue analogues (PBAs) by phytic acid etching and low-temperature gas-phase selenization. Due to the advantages of its multi-component composition and hollow structure, CoNiFe-Se exhibited a low overpotential of 275 mV@10 mA cm-2, a small Tafel slope of 62.3 mV dec-1 and a long-term stability of more than 80 h in 1.0 M KOH. This research offers an innovative idea and a straightforward technique for preparing hollow multimetallic selenide electrocatalysts derived from PBAs.
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