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ƞ6-Fluoranthene Complexes from the Reactions of Osmacyclopentadienes with Alkynes
Yue Zhao1, Yue Sun1, Bingjie Fu1
1School of Chemistry, Dalian University of Technology, Dalian, 116024, China.
Abstract:
Osmacyclopentadiene complexes were obtained from the reactions between OsCl2(PPh3)3 and 1,8-dialkynyl naphthalene compounds. These complexes exhibited paramagnetism as they adopted triplet ground states. Reactions of osmacyclopentadienes with alkynes were investigated, which produced novel η6-fluoranthene complexes, showing their potential in organometallic synthesis.
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