Synthesis and Characterization of a Novel Sol-Gel-Derived Ni-Doped TiO₂ Photocatalyst for Rapid Visible Light-Driven...

The increasing presence of pharmaceutical contaminants, such as paracetamol, in water sources necessitates the development of efficient and sustainable treatment technologies. This study investigates the photocatalytic degradation and mineralization of paracetamol under visible light using nickel-doped titanium dioxide (Ni-TiO₂) catalysts synthesized via the sol-gel method. The catalysts were characterized through Raman spectroscopy, UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), and surface area measurements. Ni doping enhanced the visible light absorption of TiO₂, reducing its band gap from 3.11 eV (undoped) to 2.49 eV at 0.20 wt.% Ni loading, while Raman analysis confirmed Ni incorporation with anatase as the predominant phase. The Ni(0.1%)-TiO₂ catalyst exhibited the highest photocatalytic activity, achieving 88% total organic carbon (TOC) removal of paracetamol (5 ppm) after 180 min under optimal conditions (catalyst dosage, 3 g L^-1). Stability tests demonstrated 84% retained efficiency over five cycles, with a kinetic rate constant of 0.010 min^-1. Hydroxyl radicals were identified as the main reactive species. The catalyst maintained high performance in tap water, achieving 78.8% TOC removal. These findings highlight the potential of Ni(0.1%)-TiO₂ as a cost-effective, visible light-active photocatalyst for the removal of pharmaceutical pollutants, with promising scalability for industrial water treatment applications.