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C3-symmetric Triple Thia/Sulfone[6]Helicene with Dual Emissions
Shuai Qiu1, Wenjing Li1, Sheng Zhang1
1Institute of Nanoscience and Engineering, Henan University, Kaifeng, 475004, P. R. China.
Abstract:
Four novel triple thia/sulfone[6]helicenes with C3 symmetry were obtained via Scholl reaction and sulfonation. Their helical structures were confirmed by X-ray crystal analysis. These helicenes show dual emission of fluorescence and phosphorescence and enantiomers BTT[6]H exhibit novel dual emission of circularly polarized luminescence (CPL) or circularly polarized phosphorescence (CPP) at 77 K.
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