Measuring carbonate dissolution rates under well-controlled conditions for reactive CO₂-water flow in a large...

This study explores the carbonate dissolution dynamics in karstic systems by simulating reactive water flow under controlled large lab-scale laboratory conditions. Using a 1 m² Jura limestone tile, the experiments focus on carbonate dissolution in fractures under variable parameters, including CO₂ concentration (0-100 %), fluid flow velocity 50-1000 ml/l) and fracture aperture (2-10 mm). This large lab-scale setup bridges the gap between field-scale phenomena and small-scale laboratory studies. Preliminary tests confirmed the suitability of the limestone for dynamic experiments, in terms of measurable calcium release at different experimental modifications. A novel, adjustable polyoxymethylene (POM) frame ensures precise control of flow and reaction boundaries. Process water with no CO₂ addition, 50% CO₂-saturation and full CO₂-saturation were used, to gain insight into the dissolution efficiency at these CO₂-saturation levels. The results showed, that the effects of different CO₂ additions were well reflected in the limestone dissolution rates. This setup provides important experimental data for the validation of numerical models for reactive transport in karst systems, to improve the understanding of the interplay between chemical reactions, fluid dynamics and geological settings. The findings have implications for karst hydrology, geochemical modeling related subsurface processes, supporting advancements in predictive capabilities for natural and engineered systems.