Polyelectrolyte complex-based materials for separations: progress, challenges and opportunities

Polyelectrolyte complex (PEC) based materials could provide a sustainable alternative to conventional materials, especially for separation applications. However, reproducible production remains a challenge due to the many parameters influencing the polyelectrolyte complexation process, eventually affecting the properties and performance of the final material. Here, we provide an overview of how different parameters affect polyelectrolyte complexation and discuss promising PEC-based materials for separation applications, i.e., porous membranes, functional and barrier coatings, adhesives, saloplastics, and extraction media. Additionally, we highlight the challenges and opportunities and discuss what is needed to get to the next level. We envision that collaboration between experimentalists and theoreticians can leverage experimental datasets with accurate descriptions of all the parameters for multiscale modelling, machine learning and artificial intelligence approaches that can be used to design PEC materials and predict their properties.