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CsMgGa5S9: a diamond-like network made of mixed tetrahedral units for excellent nonlinear optical properties
Yi-Bing Huang1,2,3, Bin-Wen Liu1,4, Guo-Cong Guo1,4
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. bwliu@fjirsm.ac.cn.
Abstract:
CsMgGa5S9 features a diamond-like framework with uniformly stacked mixed tetrahedral units and embedded Cs+ ions. It exhibits a favorable second-harmonic generation response (0.5 × AgGaS2@1910 nm) and a large bandgap (3.12 eV) that yield a high laser-induced damage threshold (8.0 × AgGaS2@1064 nm), making it an excellent nonlinear optical material.
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