Biomass, Phyto-Ash, and Biochar from Beech Wood as Functional Additives for Natural Rubber-Based Elastomer Composites

The growing interest in renewable resource-based materials has driven efforts to develop elastomeric biocomposites using biomass, phyto-ash, and biochar as fillers. These bio-additives, derived from beech wood through various processing methods, were incorporated into natural rubber (NR) at varying weight ratios. The primary objective of this study was to assess how the type and content of each bio-filler influence the structural, processing, and performance properties of the biocomposites. Mechanical properties, including tensile strength and hardness, were evaluated, while crosslink density of the vulcanizates was determined using equilibrium swelling in solvents. Additionally, the composites underwent thermogravimetric analysis (TGA) to determine the decomposition temperature of individual components within the polymer matrix. Bio-fillers influenced rheological and mechanical properties, with phyto-ash reducing viscosity and cross-linking density, and biochar and biomass increasing stiffness and maximum torque. Biochar extended curing time due to the absorption of curing agents, whereas phyto-ash accelerated vulcanization. Mechanical tests showed that all bio-filled composites were stiffer than the reference, with biochar and biomass (30 phr) exhibiting the highest hardness (45.8 °ShA and 49.1 °ShA, respectively) and cross-link density (2.68 × 10^-5 mol/cm³ and 2.77 × 10^-5 mol/cm³, respectively), contributing to improved tensile strength, in particular in the case of biochar, where the TS was 17.6 MPa. The study also examined the effects of thermal-oxidative aging on the samples, providing insights into the changes in the mechanical properties of the biocomposites under simulated aging conditions.