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Laboratory Rotational Spectra of Cyanocyclohexane and Its Siblings (1- and 4-Cyanocyclohexene) Using a Compact
Gabi Wenzel1, Martin S Holdren1, D Archie Stewart1
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.
Abstract:
Chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy is a versatile technique to record broadband gas-phase rotational spectra, enabling detailed investigations of molecular structure, dynamics, and hyperfine interactions. Here, we present the development and application of a CP-FTMW spectrometer operating in the 6.5-18 GHz frequency range, studying cyanocyclohexane, 1-cyanocyclohexene, and 4-cyanocyclohexene using a heated pulsed supersonic expansion source. The dynamic range, experimental resolution, and high sensitivity enable observation of multiple conformers, precise measurements of hyperfine splitting arising from nuclear quadrupole coupling due to the nitrogen atom in the cyano group, as well as the observation of singly 13C- and 15N-substituted isotopic isomers in natural abundance. Using the latter, precise structures for the molecules are derived. The accurate rotational spectra enabled a search for these species toward the dark, cold molecular cloud TMC-1; no signals are found, and we discuss the implications of derived upper limits on the interstellar chemistry of the cyanocyclohexane family.
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