Efficient remediation and synchronous recovery of uranium by phosphate-functionalized magnetic carbon-based flow...

Through the design of flow electrodes, flow electrode capacitive deionization (FCDI) enables the efficient remediation of uranium-contaminated water to meet World Health Organization (WHO) standards (uranium ≤ 30 ppb), while concurrently facilitating the recovery of uranium from the flow electrode slurry. In this work, the phosphate-functionalized magnetic carbon-based flow electrode (OMPAC) was synthesized by simply co-precipitation and oxygen plasma treatment. The enhanced conductivity of OMPAC accelerated the efficient remediation of surface water contaminated with multiple nuclides, due to the improved charge-transfer capability facilitated by the introduced magnetic particles (Fe, Fe₃O₄, Fe₃C) and heteroatoms (O, P). The uranium in feed solution was selectively adsorbed by OMPAC in flow electrode slurry, benefiting from the multiple strong sorption interactions between U(VI) and C=O/P=O/P-O groups, as well as the redox reactions between U(VI) and Fe (0/II). After four batch cycles, the average uranium removal rate by OMPAC was maintained at 97.84 %, while the recovery rate of uranium from OMPAC reached 78.2 %, demonstrating the excellent long-term performance and synchronous uranium recovery capability in FCDI. This study provides feasibility guidance for the remediation of radioactive pollution and the strategic reuse of resources via the FCDI technology.