Influences of Additives on the Rheological Properties of Cement Composites: A Review of Material Impacts

Cement-based materials are essential in modern construction, valued for their versatility and performance. Rheological properties, including yield stress, plastic viscosity, and thixotropy, play indispensable roles in optimizing the workability, stability, and overall performance of cement composites. This review explores the effects of supplementary cementitious materials (SCMs), chemical admixtures, nanomaterials, and internal curing agents on modulating rheological properties. Specifically, SCMs, including fly ash (FA), ground granulated blast furnace slag (GGBFS), and silica fume (SF), generally improve the rheology of concrete while reducing the cement content and CO₂ emissions. Regarding chemical admixtures, like superplasticizers (SPs), viscosity-modifying agents (VMAs), setting-time control agents, and superabsorbent polymers (SAPs), they further optimize flow and cohesion, addressing issues such as segregation and early-age shrinkage. Nanomaterials, including nano-silica (NS) and graphene oxide (GO), can enhance viscosity and mechanical properties at the microstructural level. By integrating these materials above, it can tailor concrete for specific applications, thereby improving both performance and sustainability. This review presents a comprehensive synthesis of recent literature, utilizing both qualitative and quantitative methods to assess the impacts of various additives on the rheological properties of cement-based materials. It underscores the pivotal roles of rheological properties in optimizing the workability, stability, and overall performance of cement composites. The review further explores the influences of SCMs, chemical admixtures, nanomaterials, and internal curing agents on rheological modulation. Through the strategic integration of these materials, it is possible to enhance both the performance and sustainability of cement composites, ultimately reducing carbon emissions and advancing the development of eco-friendly construction materials.