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Published on: October 15, 2015
Direct Electrosynthesis and Separation Platform for Chlorine from Saline Water
Jianan Gao1,2, Qingquan Ma3, Yihan Zhang1
1Department of Civil and Environmental Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, United States.
This study presents a novel electrosynthesis platform for producing and separating chlorine from brines and seawater. The technology offers efficient wastewater valorization and water purification, meeting environmental standards.
Area of Science:
- Electrochemistry
- Environmental Science
- Chemical Engineering
Background:
- Electrosynthesis of chlorine from saline sources offers wastewater valorization and water purification.
- Challenges include effective chlorine separation and mitigating environmental impacts of chlorine derivatives.
Purpose of the Study:
- To develop a scalable electrosynthesis platform for simultaneous chlorine production and separation from brines.
- To achieve high selectivity and separation efficiency while ensuring environmental compliance of treated brine.
Main Methods:
- Utilized a three-phase interface electrosynthesis platform.
- Employed a three-stacked modular electrolyzer for chlorine generation.
- Tested with real reverse osmosis retentate and seawater.
Main Results:
- Achieved up to 97% selectivity and nearly 100% separation efficiency for chlorine.
- Successfully generated sodium hypochlorite solutions at 0.53 and 5.1 wt %.
- Treated brine discharge met stringent environmental standards for chlorine-based contaminants.
Conclusions:
- The developed platform enables efficient, scalable chlorine production and separation from saline wastewater.
- This process advances decentralized chlor-alkali production and nonpotable water generation.
- Integration with water splitting offers improved efficiency and safety compared to conventional methods.
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