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Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes
Wenyan Tian1, Yongyue Luo1, Siwen Zhu1
1College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, PR China. zcj123@swu.edu.cn.
Dalton Transactions (Cambridge, England : 2003)
|May 9, 2025
Abstract:
Dual metal complexes, Pd(PPh3)4 and Ir(ppy)2(dtbbpy)PF6, are simultaneously anchored onto SiO2-grafted poly(4-vinyl benzyl chloride) (PVBC) brushes via Friedel-Crafts alkylation in one pot, affording supported dual Pd/Ir complexes which gave good yields in photocatalytic α-allylation.

