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(C7H3NO4)2Sb2F2·2H2O: a pyridine-based compound shows large optical anisotropy
Yaoguo Shen1, Jiajia Xiong1, Yiman Yang1
1College of Physics and Electronic Information Engineering, Minjiang University, Fuzhou, Fujian 350108, China. shenyg@mju.edu.cn.
Abstract:
A new organic-inorganic hybrid compound, (C7H3NO4)2Sb2F2·2H2O, was synthesized. It has two-dimensional [C14H10F2N2O10Sb2]∞ parallel layers, which are further optimally aligned by the π-π conjugation mode. Remarkably, this compound exhibits a large birefringence (0.40@550 nm), surpassing those of most of the other pyridine-derived birefringent materials reported so far.
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