Sb³⁺-Doped Rb₂HfCl₆ Perovskites as High-Performance Thermally Stable Single-Component Phosphors for White...

Stable and efficient inorganic lead-free double perovskites are crucial for high-reliability optoelectronic devices. However, dual-doped perovskite phosphors often suffer from poor color stability due to differences in thermal activation energies and electron-phonon interactions between the doped ions. To address this, single-doped Sb³⁺-incorporated Rb₂HfCl₆ perovskite crystals were synthesized via a co-precipitation method. Under UV excitation, Rb₂HfCl₆:Sb exhibits broad dual emission bands, attributed to singlet and triplet self-trapped exciton radiative transitions induced by Jahn-Teller distortion in [SbCl₆]^3- octahedra. This dual emission endows the material with high sensitivity to excitation wavelengths, enabling tunable luminescence from cyan to orange-red across 400-800 nm. Utilizing this dual emission, a white LED was fabricated, showcasing a high color rendering index and excellent long-term stability. Remarkably, the material exhibits breakthrough thermal stability, maintaining more than 90% of its emission intensity at 100 °C, while also exhibiting remarkable resistance to humidity and oxygen exposure. Compared to co-doped phosphors, Rb₂HfCl₆:Sb offers advantages such as environmental friendliness, simple fabrication, and stable performance, making it an ideal candidate for WLEDs. This study demonstrates notable progress in developing thermally stable and reliable optoelectronic devices.