Influence of Silicate Modulus and Eggshell Powder on the Expansion, Mechanical Properties, and Thermal Conductivity...

To address the demands of the low-carbon era, this study proposed a solution by using eggshell powder (ESP), fly ash, and ground granulated blast furnace slag together with alkaline solution in the preparation of lightweight geopolymer foam concrete (LWGFC). The aim of this study is to investigate the influence of replacing precursor materials with 5-20% ESP on the expansion behavior, physical, mechanical characteristics, and thermal conductivity of LWGFC. Additionally, the study examines the effect of varying the silicate modulus (SiO₂/Na₂O ratios of 1.0, 1.25, and 1.5) on the properties of LWGFC. Incorporating ESP from 5% to 20% with a constant SiO₂/Na₂O ratio reduced the initial setting time, while a high SiO₂/Na₂O ratio controlled the setting time and expansion volume. The high SiO₂/Na₂O ratio decreased the porosity and enhanced the compressive strength of the LWGFC but increased the thermal conductivity. The inclusion of more than 10% ESP content negatively affected compressive strength; however, a high SiO₂/Na₂O ratio can mitigate this detrimental effect. The thermal conductivity of optimal-content ESP mixtures with a SiO₂/Na₂O ratio of 1.0 was about 0.84 W/m·K, which is 2.1% lower than mixtures with a ratio of 1.25 and 18.6% lower than those with a ratio of 1.5. High-content ESP mixtures had a density of 1707 kg/m³, 0.97 W/m·K, and a compressive strength of 18.9 MPa at a low SiO₂/Na₂O ratio. Finally, the inclusion of ESP in the LWGFC, along with the use of an appropriate silicate modulus, resulted in improved strength development while decreasing porosity.