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Updated: May 16, 2025

Microwave-Assisted Preparation of 1-Aryl-1H-pyrazole-5-amines
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Published on: June 23, 2019

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Aryne Polymerization Enabled by Pyrazole-Induced Nucleophilic Aromatic Substitution.

Hayato Fujimoto1,2, Shisato Yamamura1, Mamoru Tobisu1,2

  • 1Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|May 14, 2025
PubMed
Summary

This study introduces a novel method for polymerizing arynes, overcoming their instability. Using N-arylpyrazole initiators, this technique creates well-defined poly(ortho-arylene)s with controlled structures.

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