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Updated: Sep 20, 2025

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
Published on: June 8, 2016
Core-Cross-Linked Micellar Nanoreactors for Biaryl Synthesis in Water: Influence of Topological Structures on
Yue Wang1, Yicen Ge1, Yu Long1
1College of Materials, Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan, 610059, China.
Abstract:
Multiple block copolymers bearing PDMAEMA (poly(2-(dimethylamino)ethyl methacrylate), PLMA (poly(lauryl methacrylate), and PAMA (poly(allyl methacrylate) segments are synthesized via RAFT (reversible addition-fragmentation chain transfer) polymerization. Manipulating the cross-linkage of PAMA in the specific domain of polymeric assemblies affords micellar nanoreactors with different topological structures. After embedded with Pd NPs (nanoparticles) in the corona layer, the core-cross-linked micelles demonstrate profound catalytic activity and structural stability in the aqueous Suzuki-Miyaura coupling of aryl bromides with aryl boronic acids.
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