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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Enantioselective palladium photoredox catalysis
Sheng Tang1, Runquan Kang1, Zhenyu Zhang1
1State Key Laboratory of Analytical Chemistry for Life Science, Jiangsu Key Laboratory of Advanced Organic Materials, Chemistry and Biomedicine Innovation Center (ChemBIC), School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China. yushouyun@nju.edu.cn.
Abstract:
The merger of visible light and transition metal catalysis, particularly palladium catalysis, has unlocked new opportunities and challenges in asymmetric synthesis. This review highlights recent advances in enantioselective palladium photoredox-catalyzed transformations, focusing on two key catalytic modes: dual palladium/photoredox catalysis and photoexcited palladium catalysis. Furthermore, it offers a comprehensive analysis of the substrate scope and reaction mechanisms reported in recent studies.
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