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Updated: Jun 13, 2025

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
Published on: April 1, 2013
Recent advances in functionalized cycloparaphenylenes: from molecular design to applications
Xiaonan Li1, Shengzhu Guo1, Hua Jiang1
1College of Chemistry, Beijing Normal University, Beijing 100875, P.R. China. jiangh@bnu.edu.cn.
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Cycloparaphenylenes (CPPs), which feature a radial π-system, have attracted considerable attention due to their size-dependent photophysical properties and distinctive curved π-conjugated cavity. Incorporating aromatic systems beyond benzene enables precise tuning of their optoelectronic properties to meet specific requirements in supramolecular chemistry and materials science. In this review, we systematically summarize the synthesis, properties, and functional applications of CPP derivatives in chiral materials, supramolecular chemistry, and photoelectric devices. It is anticipated that this review will provide valuable insights for researchers working on CPP derivatives and carbon nanohoops, and contribute to the advancement of synthetic chemistry and materials chemistry.
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