Jove
Visualize
Contact Us

Related Concept Videos

Molecular Shape and Polarity03:37

Molecular Shape and Polarity

59.8K
Dipole Moment of a Molecule
59.8K
Induced Electric Dipoles01:28

Induced Electric Dipoles

4.2K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.2K
Intermolecular Forces03:13

Intermolecular Forces

58.0K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.0K
Polarity of the Cytoskeleton01:18

Polarity of the Cytoskeleton

16.5K
The intrinsic polarity of cells can be primarily attributed to two factors- i) the asymmetric accumulation of mobile components such are regulatory molecules and subcellular components across the cell and ii) the orientation of polar cytoskeletal filaments that make up the cytoskeletal networks, specifically microfilaments, and microtubules arranged along the axis of polarity. Interactions between the cytoskeletal filaments are crucial for the establishment and maintenance of the polar nature...
16.5K
Solubility03:00

Solubility

17.3K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.3K
Solvating Effects02:12

Solvating Effects

7.4K
An understanding of the solvating effect helps rationalize the relation between solvation and acidity of the compound. In addition, this also explains the relative stability of conjugate bases for compounds with different pKa values. This lesson details, in-depth, the principle of solvating effects. The strength of an acid and the stability of its corresponding conjugate base are determined using pKa values. This observed relationship is a consequence of solvation, which is the interaction...
7.4K
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies
  1. Home
  2. Impact Of Solvent Polarity On The Photoinduced Dynamics Of A Push-pull Molecular Motor.
  1. Home
  2. Impact Of Solvent Polarity On The Photoinduced Dynamics Of A Push-pull Molecular Motor.

Related Experiment Video

Light-driven Molecular Motors on Surfaces for Single Molecular Imaging
08:40

Light-driven Molecular Motors on Surfaces for Single Molecular Imaging

Published on: March 13, 2019

11.3K

Impact of solvent polarity on the photoinduced dynamics of a push-pull molecular motor.

Davide Accomasso1, Dominika Makoś1

  • 1Faculty of Chemistry, University of Warsaw, Pasteura 1, Warsaw, Poland.

The Journal of Chemical Physics
|June 13, 2025

View abstract on PubMed

Summary
This summary is machine-generated.

Researchers studied light-driven molecular motors, revealing that polar solvents like methanol accelerate their photoisomerization dynamics. This is due to solvent effects stabilizing charge-transfer states, impacting motor efficiency and fluorescence.

More Related Videos

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
09:42

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes

Published on: January 16, 2016

9.0K
Molecular Entanglement and Electrospinnability of Biopolymers
07:59

Molecular Entanglement and Electrospinnability of Biopolymers

Published on: September 3, 2014

14.6K

Related Experiment Videos

Light-driven Molecular Motors on Surfaces for Single Molecular Imaging
08:40

Light-driven Molecular Motors on Surfaces for Single Molecular Imaging

Published on: March 13, 2019

11.3K
Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
09:42

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes

Published on: January 16, 2016

9.0K
Molecular Entanglement and Electrospinnability of Biopolymers
07:59

Molecular Entanglement and Electrospinnability of Biopolymers

Published on: September 3, 2014

14.6K

Area of Science:

  • Photochemistry
  • Molecular Dynamics
  • Supramolecular Chemistry

Background:

  • Light-driven rotary molecular motors convert light energy into directed rotation.
  • Overcrowded alkene motors utilize photoisomerization and thermal inversion for motion.
  • The precise photoisomerization mechanisms in these motors remain incompletely understood.

Purpose of the Study:

  • To investigate the photoinduced dynamics of a push-pull alkene molecular motor.
  • To elucidate the influence of solvent polarity on the motor's photorelaxation pathways.
  • To compare dynamics in nonpolar (cyclohexane) and polar (methanol) solvents.

Main Methods:

  • Quantum chemical calculations.
  • Quantum mechanics/molecular mechanics nonadiabatic dynamics simulations.
  • Analysis of excited-state pathways and energy landscapes.
  • Main Results:

    • The primary photorelaxation pathway involves two distinct excited-state minima in both solvents.
    • Polar methanol significantly accelerates photorelaxation compared to nonpolar cyclohexane.
    • Methanol lowers the energy barrier between excited states and reduces the ground-state energy gap at the decay point.

    Conclusions:

    • Solvent polarity, specifically methanol's, stabilizes the charge-transfer excited state, enhancing photorelaxation.
    • Accelerated dynamics in methanol correlate with faster fluorescence decay and reduced forward photoisomerization yield.
    • Understanding solvent effects is crucial for optimizing molecular motor performance.