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Ball-Milled Spent Coffee Ground Biochar Effectively Removes Caffeine from Water.

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Spent coffee ground biochar, enhanced by ball milling, effectively removes caffeine from water. This sustainable material shows high adsorption capacity and efficiency in continuous flow systems.

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Area of Science:

  • Environmental Science
  • Materials Science
  • Water Treatment

Background:

  • Caffeine is an emerging contaminant in aquatic ecosystems, posing environmental risks.
  • Spent coffee grounds (SCG) are abundant waste materials with potential for valorization.

Purpose of the Study:

  • To investigate the efficacy of SCG-derived biochars for caffeine adsorption.
  • To optimize biochar properties through pyrolysis and ball milling for enhanced caffeine removal.

Main Methods:

  • Spent coffee grounds were pyrolyzed at various temperatures (300, 450, 600 °C) to produce biochars.
  • Biochars were ball-milled to increase surface area and functional groups.
  • Batch and continuous flow experiments were conducted to assess caffeine adsorption.

Main Results:

  • Ball-milled biochars pyrolyzed at 450 °C (BMCG450) exhibited the highest caffeine adsorption capacity (82.65 mg/g).
  • Ball milling significantly increased biochar surface area and oxygen-containing functional groups.
  • Caffeine adsorption was influenced by pH and ionic strength, with optimal removal under specific conditions.

Conclusions:

  • Ball-milled SCG biochar (BMCG450) is a promising, cost-effective sorbent for caffeine removal from water.
  • The material demonstrates high adsorption efficiency in both batch and continuous flow setups.
  • This research offers a sustainable approach to managing caffeine pollution in aquatic environments.