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Updated: Sep 18, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Shape-Matching and Halogen Bonding in Chiral Pyrazine-Allene Hosts: Confining an Unstable Guest Conformation

Víctor Rubio-Pisabarro1, Jonathan Álvarez-García1, María Magdalena Cid1

  • 1Departamento de Química Orgánica, Edificio Ciencias Experimentais, Universidade de Vigo, E-36310 Vigo, Spain.

Organic Letters
|June 24, 2025
PubMed

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The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal...
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