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Order-Disorder-Type Transitions Through a Multifractal Procedure in Cu-Zn-Al Alloys-Experimental and Theoretical
Constantin Plăcintă1, Valentin Nedeff2, Mirela Panainte-Lehăduş3
1Department of Materials Science, Faculty of Material Science and Engineering, "Gheorghe Asachi" Technical University of Iasi, Blvd. Prof. Dr. D. Mangeron, No. 41, 700050 Iași, Romania.
Abstract:
Experimental and theoretical design on thermal and structural properties of Cu-Zn-Al alloys are established. As such, from an experimental point of view, differential thermal analysis has been performed with the help of a DSC Netzsch STA 449 F1 Jupiter calorimeter with high levels of sensitivity, and the structural analysis has been accomplished through X-ray diffraction and SEM analysis. An unusual specific property for a metallic material has been discovered, which is known as "rubber-type behavior", a characteristic determined by micro-structural changes. From the theoretical point of view, the thermal transfer in Cu-Zn-Al is presented by assimilating this alloy, both structurally and functionally, with a multifractal, situation in which the order-disorder transitions assimilated with thermal "dynamics" of Cu-Zn-Al, are mimed through transitions from non-multifractal to multifractal curves. In such a context, the thermal expansion velocity contains both the propagation speed of the phase transformation (be it a direct one: austenitic-martensitic transformation, or an indirect one: martensitic-austenitic transformation) and the thermal diffusion speed. Then, through self-modulations of the thermal field, the Cu-Zn-Al alloy will self-structure in channel-type or cellular-type thermal patterns, which can be linked to obtained experimental data. Consequently, since the thermal conductivity becomes a function of the observation scale, and heat transfer is modified to reflect the multifractal, non-differentiable paths in the material, it leads to anomalous diffusion and complex thermal behaviors.
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