Harnessing BiOI/V₂O₅ Nanocomposites: Advanced Bifunctional Catalysts for Visible-Light Driven Environmental...

Efficient photocatalysts based on composite materials are essential for addressing environmental pollution and enhancing water purification. This study presents a novel BiOI/V₂O₅ nanocomposite (BVNC) with a flower-like layered structure, synthesized via a low-temperature solvothermal process followed by high-pressure annealing for visible light (VL)-driven dye degradation and antibacterial activities. Compared to individual BiOI nanoparticles (BOINP) and V₂O₅ nanoparticles (VONP), under VL, the BVNC demonstrated significantly enhanced photocatalytic and antibacterial activity. The best-performing BVNC achieved a remarkable methylene blue degradation efficiency of 95.7% within 140 min, with a rate constant value 439% and 430% of those of BOINP and VONP, respectively. Additionally, BVNC exhibited high photocatalytic efficiencies for rhodamine 6G (94.0%), methyl orange (90.4%), and bisphenol A (69.5%) over 160 min, highlighting the superior performance of the composite materials for cationic and anionic dyes. Furthermore, BVNC established outstanding antibacterial capability against Staphylococcus aureus and Escherichia coli, demonstrating zones of inhibition of 12.24 and 11.62 mm, respectively. The improved catalytic and antibacterial capability is ascribed to the presence of a robust p-n heterojunction between BOINP and VONP, which broadens the photo-absorption range, reduces bandgap energy, and facilitates the significant separation of excitons and faster release of reactive oxygen species.