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Updated: Sep 12, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Reaction-driven magmatic crystallisation at the Maoniuping carbonatite
1State Key Laboratory of Deep Earth and Mineral Exploration, Institute of Geology, Chinese Academy of Geological Sciences, Beijing, PR China. ly@cags.ac.cn.
The Maoniuping rare earth element (REE) deposit formed magmatically from a carbonatite brine-melt, not hydrothermal fluids. Assimilation of host rock elements drove solidification, a process likely common in other carbonatite-hosted REE deposits.
Area of Science:
- Geology
- Economic Geology
- Petrology
Background:
- Igneous rocks form from magma solidification, with hydrothermal alteration often proposed for mineral deposits.
- The origin of the Maoniuping rare earth element (REE) deposit has been attributed to hydrothermal processes, but direct evidence is lacking.
- Understanding the genesis of REE deposits is crucial for global resource management.
Purpose of the Study:
- To investigate the formation mechanism of the Maoniuping REE deposit.
- To determine the role of magmatic versus hydrothermal processes in REE mineralization.
- To elucidate the solidification process of carbonatite melts in relation to host rock interaction.
Main Methods:
- Detailed textural and chemical analysis of rock samples from the Maoniuping deposit.
- Microscopic examination to identify mineral assemblages and interactions.
- Geochemical investigation of melt-host rock interactions and element assimilation.
Main Results:
- The Maoniuping REE deposit originated from a magmatic carbonatite brine-melt, not hydrothermal fluids.
- Interaction between the carbonatite melt and quartz syenite host produced albitised fenites.
- Coupled metasomatism led to silica contamination, causing melt solidification through the crystallization of refractory silicates (antiskarn) and removal of Na and K.
Conclusions:
- Carbonatite melts can solidify via element assimilation from their environment, a process distinct from simple cooling or volatile exsolution.
- Solidification driven by coupled antiskarnisation and fenitisation influences mineral assemblage and ore fabric.
- This igneous formation process is likely significant for many carbonatite-hosted REE deposits globally.
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